Cationic Softener • The simplest cationic are the primary, secondary and tertiary mono-amines and their salts, formed by neutralization of the amines, usually with acetic acid.
• Reaction, with alkylating like methyl chloride, benzyl chloride, dimethyl sulphate, etc converts the insoluble amines into water soluble salts, which are more active than the original amines.
Mode of action: • When a quaternary ammonium softener is dissolved in water, it ionizes into a hydrophilic head with a negative charge and a hydrophobic tail carrying a positive charge. On the other hand, when textile fibers are entered into water they acquire a negative charge.
When a textile fiber is entered into an aqueous solution of a cationic softener.
• During the softening treatment the negative charge on the fiber surface attracts the positive tail of the cationic softener. This result in firmly anchoring of the softener residue on the fiber substance, somewhat similar to sheathing the fiber with an oily film. This is responsible for obtaining a soft handle and a pliable, well lubricated fiber surface.
Properties of cationic softener:
• They are compatible with most resin finishes.
• It has tendency to change the shade.
• It also affects the fastness of certain dyestuffs.
• It also causes discoloration on white fabrics.
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