Water-in-oil emulsions are considered to be special liquid-in-liquid colloidal dispersions. Their kinetic stability is a consequence of small droplet size and the presence of an interfacial film around water droplets and is caused by stabilizing agents (or emulsifiers). These stabilizers suppress the mechanisms involved that would otherwise break down an emulsion. Such mechanisms include:
Sedimentation is the falling of water droplets from an emulsion because of the density difference between the oil and water. Aggregation or flocculation is the grouping together of water droplets in an emulsion without a change in surface area. Coalescence is the fusion of droplets to form larger drops with reduced total surface area.
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Oil emulsions
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